Substation x formers are AC. There are DC systems out there like mass transit trains, construction cranes, power shovels etc. but are fed from an AC source and not generally associated with a distribution system in that they are not used to express feed they are considered line loss for power quality.
There are a number of high voltage DC used for inter grid connections as well as transmitting power from some large generating projects like wind farms to a regional grid. High voltage DC is significantly more efficient than high voltage AC over long distances.